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Journal of Organometallic Chemistry

Journal of Organometallic Chemistry

Volume 394
Main Index

Issues 1-3, Pages 1-794 (11 August 1990)


Introduction: biographical note
Pages xiii-xiv
E. W. Abel
The interconversion of oxo and imido ligands at a dimolybdenum centre: X-ray crystal structure of [Mo(η-C5H4Me)(NPh)(μ-NPh)]2
Pages c9-c15
Malcolm L. H. Green, Graeme Hogarth, Peter C. Konidaris, Philip Mountford
Diisopropylaminomethylidyne complexes of iron, chromium, molybdenum and tungsten
Pages c24-c26
Stephen Anderson, Anthony F. Hill
Subject index
Pages c41-c48
Author index
Pages c39-c40
X-ray crystal structure of the dimethylgallium azide polymer and its use as a gallium nitride precursor
Pages c6-c8
David A. Atwood, Richard A. Jones, Alan H. Cowley, Jerry L. Atwood and, Simon G. Bott
Synthesis of Pt(II)-η3-benzyl complexes: crystal structure of [Pt(Bu2tP(CH2)3PBu2t)(η3-anti-1-MeCHC6H4Br-4)][BF4]
Pages c35-c38
L. e. Crascall, S. A. Litster, A. D. Redhouse, J. L. Spencer
Photochemistry of trichloro(carbonyl)-tris(dimethylphenylphosphine)rhenium(III) in low temperature media
Pages c21-c23
Antony J. Rest, Mark J. Wilson, E. Cecilia Barra and, Patricio G. Reveco
A novel slipped tripledecker complex with a 3,4-diborafulvene as bridging ligand
Pages c1-c5
G. E. Herberich, C. Ganter, L. Wesemann, R. Boese
Addition of electrophiles to metalladiborane anions [M(CO)42-B2H5)] (Fe, Ru, Os)
Pages c27-c30
Tim. J. Coffy, Sheldon G. Shore
Structural characterization of a tetranuclear tungsten carbide cluster formed by the reductive cleavage of carbon monoxide: W44-C)(OCH2-c-C5H9)14
Pages c16-c20
Malcolm H. Chisholm, Charles E. Hammond, John C. Huffman, Victor J. Johnston
Carbon—hydrogen activation by metal carbonyl complexes induced by dinitrogen monoxide
Pages c31-c34
Carlos Barrientos, Chanchal K. Ghosh, William A. G. Graham, Marian J. Thomas
The chemistry of monoanionic carbaborane ligands. Synthesis, and molecular and electronic structure of [3,3,3-(CO)3-4-SMe2-3,1,2-MnC2B9H10], and order-of-magnitude improved structure of (η-C5H5)Mn(CO)3
Pages 1-13
Jill Cowie, Ewan J. M. Hamilton, Jill C. V. Laurie, Alan J. Welch
Synthesis of metal-rich metallaborane clusters. Evidence for a mechanism involving fragment condensation
Pages 15-27
Xiangsheng Meng, Ananda K. Bandyopadhyay, Thomas P. Fehlner, Friedrich-Wilhelm Grevels
Synthesis and molecular structure of closo-3-(η6-C6H6)-3,1,2-FeC2B9H11
Pages 29-36
Sharon S. Lee, Carolyn B. Knobler, M. Frederick Hawthorne
La bromodésilylation des fluorovinylsilanes
Pages 37-44
Thierry Gouyon, Raymond Sauvêtre, Jean. -F. Normant
Reactions of tetramesityldisilene with azides: Synthesis of disilaaziridines
Pages 45-55
Gregory R. Gillette, Robert West
Silylmethyl and related complexes VIII. Bis[bis(trimethyl)silylmethyl]manganese(II): Its synthesis, properties, and crystal structures of its tetrahydrofuran and bis(dimethylphosphino)ethane adducts
Pages 57-67
Peter B. Hitchcock, Michael F. Lappert, Wing-Por Leung, Nabeel H. Buttrus
Desilylation and cyclometallation reactions of diphenyl{tris(trimethylsilyl)methyl}phosphine with platinum(II) compounds. Crystal structure of trans-[imageH2{PPh2CH(SiMe3)2}]
Pages 69-75
Salih S. Al-Juaid, Colin Eaborn, Peter B. Hitchcock, J. David Smith, Livio Zanotto, Pramesh N. Kapoor
Synthesis of aryltin(IV) complexes using arylmercury compounds. Synthesis of mixed triaryltin(IV) complexes. Crystal and molecular structure of [SimagePh)Ph2Cl]
Pages 77-85
José Vicente, Maria Teresa Chicote, Maria del Carmen Ramirez-de-Arellano, Peter G. Jones
Synthesis and reactivity of bis(trimethylsilyl)cyclopentadienyl samarium complexes including the X-ray crystal structure of [(Me3Si)2C5H3]3Sm
Pages 87-97
William J. Evans, Roy A. Keyer, Joseph W. Ziller
Zirconoxycarbene complexes obtained by regioselective coupling of (isoprene)zirconocene with hexacarbonyltungsten and a ketone. Crystal structure of Cp2imageH2
Pages 99-112
Gerhard Erker, Friedrich Sosna, Ronald Pfaff, Ralf Noe, Christian Sarter, Arno Kraft, Carl Krüger and, Roland Zwettler
1,3-Dichalcogena-2-vanada-[3]ferrocenophanes
Pages 113-120
Max Herberhold, Matthias Schrepfermann, Arnold L. Rheingold
The ketenylidene route to mixed-metal carbide clusters: [MnRu3C(CO)13], [MnOs3C(CO)13], [Cr2Ru3C(CO)16]2−, [Mo2Ru3C(CO)16]2−, [Rh3Ru3C(CO)15], [Ni3Ru3C(CO)13]2− and [Co3Ru3C(CO)15]
Pages 121-143
Michael P. Jensen, William Henderson, Dean H. Johnston, Michal Sabat, Duward F. Shriver
An NMR spectroscopic and EHMO investigation of cationic mixed metal clusters: X-ray crystal structure of (1,7,7-trimethyl-μ2-2-propynylnorbornene)-bis(cyclopentadienyl)tetracarbonyldimolybdenum
Pages 145-166
Michael F. D'Agostino, Christopher S. Frampton, Michael J. McGlinchey
Heteronuclear transition metal-alkyne clusters : III. Alkyne assisted formation of molybdenum-iron bonds. Synthesis and crystal structure of [MoFe(μ-C4Ph4)(CO)4(S2CNEt)2)2]
Pages 167-175
Heinz-Bernhard Kraatz, Michael J. Went, John C. Jeffery
Reversible insertion of alkynes into molybdenum- and tungsten-sulphur bonds
Pages 177-193
Laurence Carlton, W. A. Wan Abu Bakar, Jack L. Davidson
Photochemisches verhalten von tricarbonyl-η5:1-(2-cyclopentadiendiyl)ethyl-molybdän und -wolfram gegenüber cyclischen dienen
Pages 195-211
Cornelius G. Kreiter, Martin Wenz, Peter Bell
Oxygen tripod ligand supported molybdenum and tungsten carbyne complexes: carbon-carbon bond formation reactions. Crystal structures of [L(CO)2Wtriple bond; length as m-dashCC6H4-p-CH3] and imageL = [(C5H5)Co{P(O)(OCH3)2}3]
Pages 213-233
Wolfgang Kläui, Harry Hamers, Michel Pfeffer, André de Cian and, Jean Fischer
Electrophilic and nucleophilic reactions of complexes formed from 2,5-dithiahex-3-yne (MeSCtriple bond; length as m-dashCSMe) and tungsten carbonyls
Pages 235-250
David C. Miller, Robert J. Angelici
Further studies of the synthesis of 1-naphthols and 4-hydroxy-5,6-dimethylbenzothiophene by protonation of Cp(CO)2Wtriple bond; length as m-dashCTol and Cp(CO)2Wtriple bond; length as m-dashC(2-C4H3S) in the presence of alkynes and carbon monoxide
Pages 251-264
Kevin E. Garrett, Wu Chang Feng, Hiroyuki Matsuzaka, Gregory L. Geoffroy, Arnold L. Rheingold
A tricarbonyl, tetranuclear tungsten cluster supported by alkoxide ligands: W4(OCH2Pri)1224-CO)(CO)2
Pages 265-274
Malcolm H. Chisholm, Kirsten Folting, Victor J. Johnston, Charles E. Hammond
The stereospecific synthesis of mono- and bi-nuclear (ligand-bridged) carbonyl complexes of manganese: a review
Pages 275-283
Gabino A. Carriedo, Victor Riera
Mehrfachbindungen zwischen hauptgruppenelementen und übergangsmetallen , : LXXVIII. Über oxo- und methylimido-komplexe des rheniums mit sauerstoff-, schwefel- und stickstoffchelaten: Synthese, spaltungsreaktionen und strukturchemie
Pages 285-303
Wolfgang A. Herrmann, Dieter W. Marz, Eberhardt Herdtweck
Dialkylaminophosphorus metal carbonyls , : VIII. A new type of phosphorus-bridging carbonyl derivative containing three phosphorus atoms: crystal and molecular structure of (iPr2NP)(tBu2PP)COFe2(CO)6
Pages 305-311
R. B. King, N. K. Bhattacharyya, E. M. Holt
The synthesis and properties of heterodinuclear alkanediyl complexes of iron(II) containing molybdenum(II), tungsten(II), rhenium(I) and ruthenium(II)
Pages 313-327
Holger B. Friedrich, John R. Moss, Bridget K. Williamson
Triple-decker complexes XIV. Reactions of iron carbonyls with the triple-decker sandwich complexes (η5-C5H5)Ni(μ,η5-C2B2C)M(η5-C5H5), (M = Co, Ni). Replacement of (η5-C5H5)Ni by and insertion of the Fe(CO)3 fragment into the (η5-C5H5)---Ni bond,
Pages 329-338
Joseph Edwin, Mark W. Whiteley, Wilfried Herter, Walter Siebert
Reactions of nucleophiles with cationic bridging alkylidyne complexes
Pages 339-347
Charles P. Casey, Paul C. Vosejpka, Mark Crocker
Carbene formation from CpM(SnPh3)(CO)2 (M = Fe, Ru). Crystal structures of CpFeI(CO){=C(OEt)Ph}, CpRuI(CO){=C(OEt)Ph} and CpRuI(CO){=C(NHMe)Ph}
Pages 349-364
Harry Adams, Neil A. Bailey, Christopher Ridgway, Brian F. Taylor, Stephen J. Walters, Mark J. Winter
Some remarkable reactions of an open Ru5 cluster
Pages 365-384
Michael I. Bruce
Benzyne complexes of ruthenium: Models for dissociative chemisorption of benzene on a metal surface. Crystal structures of [Ru4(CO)10(μ-CO)(μ4-PR)(μ44-C6H4)] (R = Ph and CH2NPh2), [Ru5(CO)134-PPh)(μ56-C6H4)] and [Ru6(CO)124-PMe)232-C6H4)2]
Pages 385-415
Selby A. R. Knox, Brian R. Lloyd, David A. V. Morton, Sara M. Nicholls, A. Guy Orpen, Josep M. Viñas, Martin Weber, Geoffrey K. Williams
A phosphorus-carbon bond cleavage reaction of coordinated trimethylphosphine in (PMe3)4Ru(OC6H4Me)2
Pages 417-432
John F. Hartwig, Robert G. Bergman, Richard A. Andersen
Reaction of Ru3{μ-H, μ-O=CNMe2}(CO)10 with diarylacetylenes; synthesis and subsequent reaction of a {μ-carboxamido, μ-σ,π-vinyl}-hexacarbonyl diruthenium complex with propyne. Crystal and molecular structures of Ru2{μ-O=CNMe2,μ-σ,π-C(p-tol)=CH(p-tol)}(CO)6, and of Ru2{μ-O=CNMe2,μ-σ,π-C(CH3)=C(H)C(p-tolyl)=CH(p-tolyl)}(CO)6 (p-tol = p-CH3C6H4)
Pages 433-454
W. Krone-Schmidt, W. J. Sieber, N. M. Boag, C. B. Knobler, H. D. Kaesz
The syntheses, structures and stereodynamics of transition metal complexes of 1,1′-bis(methylthio)ruthenocene. Crystal structure of 1,1′-bis(methylthio)ruthenocene tetracarbonyltungsten
Pages 455-468
Edward W. Abel, Nicholas J. Long, Keith G. Orrell, Anthony G. Osborne, Vladimír Sik, Paul A. Bates and, Michael B. Hursthouse
Synthese, struktur und reaktivität zweikerniger hydridoverbrückter osmium-komplexe mit Os---Os-Doppel- und Dreifach-Bindung
Pages 469-479
M. Schulz, S. Stahl, H. Werner
Intermolecular and intramolecular C---H activation reactions of (η-mesitylene)osmium complexes containing tertiary phosphines
Pages 481-513
Martin A. Bennett, A. Mala M. Weerasuria
Fluxional behaviour of the clusters Os3(μ-H)2(CO)9(L), L = PMe2Ph, PMe3, PiPr3, P(o-tolyl)3 and PPh(1-naphthyl)2. Crystal structure of Os3(μ-H)2(CO)9(PiPr3)
Pages 515-531
Louis J. Farrugia
Some substitution reactions of planar hexanuclear osmium clusters
Pages 533-554
Adrian Bott, John G. Jeffrey, Brian F. G. Johnson, Jack Lewis
Enantioselective catalysis LIII. Enantioselective catalysis with Rh complexes containing optically active iron compounds as ligands. Crystal structure of CpFe(CO)(COMe)PPh2ORh(COD)
Pages 555-567
Henri Brunner, Rudolf Eder, Benedikt Hammer, Ulrich Klement
Multiple pathways in rhodium-catalyzed reactions of 1-alkynes with 3-butenoic acid
Pages 569-581
Giuseppe Salerno, Maria Panza, Gian Paolo Chiusoli and, Mirco Costa
Syntheses, structures, and reactions of alkenyl-dirhodium complexes: coupling μ-methylene and σ-vinyl to allyl; an entry to μ-ethylidene-μ-methylene dirhodium complexes. Crystal structures of [{(C5Me5Rh)(μ-CH2)(CH=CH2)}2] and [(C5Me5Rh)2(μ-CH2)(μ-CHMe)Cl2]
Pages 583-599
Jesus Martinez, John B. Gill, Harry Adams, Neil A. Bailey, Isabel M. Saez, Glenn J. Sunley, Peter M. Maitlis
Metallkomplexe mit biologisch wichtigen liganden LVI. Darstellung, struktur und reaktionen von C-allylglycin-rhodium- und -iridium-komplexen,
Pages 601-614
Ingo Zahn, Barbara Wagner, Kurt Polborn, Wolfgang Beck
Trifluoromethyl, difluorocarbene and tetrafluoroethylene complexes of iridium and the crystal structures of IrI(CH3)(CF3)(CO)(PPh3)2, Ir(CF3)(C2F4)(CO)(PPh3)2 and Ir(CF3)(=CF2)(CO)(PPh3)2
Pages 615-642
Penelope J. Brothers, Anthony K. Burrell, George R. Clark, Clifton E. F. Rickard, Warren R. Roper
Polynuclear homo- or heterometallic palladium(II) - platinum(II) pentafluorophenyl complexes containing bridging diphenylphosphido ligands. Synthesis and crystal structure of [(C6F5)2Pt(μ-PPh2)2Pt(phen)]
Pages 643-658
J. Forniés, C. Fortuño, R. Navarro, F. Martínez and, A. J. Welch
Synthesis and reactivity towards diiodine of palladium(II) and platinum(II) complexes with non-cyclic and cyclic ligands (C6H3{CH2NR1R2}2-2,6). End-on diiodine-platinum(II) bonding in macrocyclic [PtI(C6H3{CH2NMe(CH2)7MeNCH2}-2,6)(η1-I2)]
Pages 659-678
Johannus A. M. van Beek, Gerard van Koten, Guido P. C. M. Dekker, Elmo Wissing, Martin C. Zoutberg and, Caspar H. Stam
A molecular orbital study of trinuclear platinum clusters
Pages 679-698
D. Michael P. Mingos, Tom Slee
Chemistry and crystal structure of [ClPt(NMe2NHCH2CHPPh2CH2CH2PPh2)]Cl containing a tridentate ylide ligand
Pages 699-709
Xavier L. R. Fontaine, Andrew M. Herring, David P. Markham, Bernard L. Shaw, Mark Thornton-Pett
The heteronuclear cluster chemistry of the Group IB metals XIV. The influence of the P(CH2Ph)3 ligand on the metal framework structures adopted by mixed-metal clusters containing M{P(CH2Ph)3} (M = Cu or Ag) fragments. Crystal structures of [Cu2Ru43-H)2(CO)12{μ-P(CH2Ph)2-(η2-CH2Ph)}] and [Cu2Ru43-H)2(CO)12{P(CH2Ph)3}2]
Pages 711-732
Carolyn J. Brown, Paul J. McCarthy, Ian D. Salter, Kenneth P. Armstrong, Mary McPartlin and, Harold R. Powell
The synthesis and molecular structure of (Ph3PAu)2Fe(CO)3P(OEt)3: a triangular Au2Fe cluster
Pages 733-741
Larry W. Arndt, Carlton E. Ash, Marcetta Y. Darensbourg, Yui May Hsiao, Christine M. Kim, Joseph Reibenspies, Kay A. Youngdahl
Bis(diphenylphosphino)-methanide or -amide and its derivatives as ligands in gold chemistry: a review
Pages 743-756
Antonio Laguna, Mariano Laguna
Dimethylsulfoxide coordination to methylmercury tetrafluoroborate
Pages 757-764
Hubert Schmidbaur, Hans-Jürgen Öller, Siegfried Gamper, Gerhard Müller
Synthesis of mixed-mtal clusters using nickel-molybdenum and nickel-tungsten complexes as cluster building blocks
Pages 765-775
Michael J. Chetcuti, Patrick N. Cunningham, John C. Gordon, Brian E. Grant, Jacqueline Klaiss
Flexible coordination of indenyl ligands in sandwich complexes of transition metals. Molecular structures of [(η-C9R7)2M] (M = Fe, R = H, Me; M = Co, Ni, R = H): Direct measurement of the degree of slip-fold distortion as a function of d-electron count
Pages 777-794
Steve A. Westcott, Ashok K. Kakkar, Graham Stringer, Nicholas J. Taylor, Todd B. Marder